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The honest version: Glutathione has documented effects on melanin pathways

One class of cardiac glycosides, cardenolides, are found in multiple plant families, and evolved in the genus Erysimum of the Brassicaceae family between one and three million years ago, providing defense against glucosinolate (a different class of defensive metabolite)-resistant insects

Correlations between toxic Pb effects and production of Pb-induced thiol peptides in the microalga Stichococcus bacillaris

Here we found plasma levels of the glycolysis byproduct methylglyoxal (MG) were 4.4-fold higher in ICU patients upon admission that later died (n = 33), and 1.7-fold higher in ICU patients that survived (n = 32),compared to uninfected controls (n = 30)