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Chen and co-workers first presented the MnO 2 -based nanoagent with both Fenton metal ion delivery and GSH exhaustion capability (Figure 1E) (Lin et al., 2018)

Diab Care 44 , 14331442 (2021)

To a solution of methyl 3-(1-(4-methoxybenzyl)-1H-pyrazol-3-yl)-2-oxopropanoate (9.8 g, 34.0 mmol) in THF (100 mL) was added NaBH 4 (1.929 g, 51.0 mmol) at 0 C