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Standard goodness-of-fit plots for the final PK/PD model are available in Fig

In most cases the matrixins are synthesized as prepro-enzymes and secreted as inactive pro-enzymes

The irradiation of compound 1 (50 M) with white light (3.0 mW cm 2 ) resulted in a quantitative conversion of compound 1 ( t R = 10.7 min) into the oxidized compound 2 ( t R = 10.3 min, 97%) over the course of 10 min, as followed by HPLCmass spectrometry (MS) (Fig