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[] D = + 37.5 (c = 0.16, CHCl 3 ), Rf = 0.3 (hexane/acetone 6/4), 1 H NMR (400 MHz, CDCl 3 ) (ppm) 7.377.27 (m, 10 H, arom.), 7.267.20 (m, 7 H, arom.), 6.91 (6.92 (d, J = 7.6 Hz, 1 H, H-6), 5.27 (s, 1 H, H-1), 5.25 (s, 1 H, H-2), 5.01 (d, J = 7.5 Hz, 1 H, H-5), 4.93 (dd, J = 6.3, 3.5 Hz, 1 H, H-3), 4.30 (td, J = 6.8, 3.6 Hz, 1 H, H-4), 3.823.77 (m, 1 H, H-5a), 3.72 (dd, J = 13.7, 7.3 Hz, 1 H, H-5b), 2.83 (s, 3 H, thioAc C H 3 ), 1.49 (s, 3 H, i -propylidene C H 3 ), 1.32 (s, 3 H, i -propylidene C H 3 )

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this supports its potential as an alternative to traditional oral medication for hypertension management

Joshua Kritzer, an associate professor of chemistry at Tufts University, says the study offers evidence that the stapled peptide approach is worth pursuing and could lead to new drugs that interfere with specific protein interactions